Depolymerization of lignin: Recent progress towards value-added chemicals and biohydrogen production.

The need for alternative sources of energy became increasingly urgent as demand for energy and the use of fossil fuels both soared. When processed into aromatic compounds, lignin can be utilized as an alternative to fossil fuels, however, lignin's complex structure and recalcitrance make depolymerization impractical. This article presented an overview of the most recent advances in lignin conversion, including process technology, catalyst advancement, and case study-based end products. In addition to the three established methods (thermochemical, biochemical, and catalytic depolymerization), a lignin-first strategy was presented. Depolymerizing different forms of lignin into smaller phenolic molecules has been suggested using homogeneous and heterogeneous catalysts for oxidation or reduction. Limitations and future prospects of lignin depolymerization have been discussed which suggests that solar-driven catalytic depolymerization through photocatalysts including quantum dots offers a unique pathway to obtain the highly catalytic conversion of lignin.

Triggering photo fermentative biohydrogen production through NiFe2O4 photo nanocatalysts with various excitation sources.

The triggering effects of nickel ferrite (NiFe2O4) photo nanocatalysts on photo fermentative hydrogen production (PFHP), and metabolic pathways under various excitation sources (incandescent lamp, Xenon lamp, and 532 laser) have been investigated. Compare to the control group (CG) highest cumulative hydrogen volume (CHV) and the maximum hydrogen production rate (HPR) of 568.8 mL and 9.17 mL/h, respectively were achieved at a loading centration of 150 mg/L excited with an incandescent lamp. The change in metabolites with NiFe2O4 incorporation suggests that bacterial activity is significantly affected by photo nanocatalysts. Triggering of NiFe2O4 by laser excitation showed the highest HPR of 7.83 mL /h within 24 h, which greatly reduces the lag time. The microbial community investigation showed that the addition of NiFe2O4 photo nanocatalysts and the change of light source effectively improved the microbial community structure and increased the abundance of hydrogen-producing bacteria (HPB) which leads to enhanced hydrogen production.

Advances in the catalyzed photo-fermentative biohydrogen production through photo nanocatalysts with the potential of selectivity, and customization.

Photo nanocatalyst have shownpromise in a variety of fields, including biohydrogen production where their catalytic efficiency is related to size, surface-to-volume ratio, and increasing the number of atoms on the surface. They can harvest solar light to create electron-hole pairs which is the key mechanism to define its catalytic efficiency, thus requiring suitable excitation wavelength, band energy, and crystal imperfections. In this review, a discussion on the role of photo nanocatalysts to catalyze biohydrogen production has been carried out. Photo nanocatalysts feature a large bandgap, andhigh defect concentration, thus having the ability to be tuned for their characteristics. Customization of the photo nanocatalyst has been addressed. Mechanism of the photo nanocatalysts in catalyzing biohydrogen has been discussed. Limiting factors of photo nanocatalysts were highlighted and several recommendations have been made to enhance the effective utilization of these photo nanocatalysts to enhance photo-fermentative biohydrogen production from biomass wastes.